Studies on Mechanical, Thermal, Optical, Physical Properties and Characterization of EVA-PLA blend Films with EGMA Compatibilizer

Authors

Keywords:

, EVA, PLA, EGMA, TSC Extruder, Blown film extrusion, Testing of Properties and Characterization.

Abstract

                                             AbstractPLA has received substantial interest recently due to it’s  Biodegradability, High strength and renewable origin. But it is amorphous and hence Brittle like PS, PVC. Hence EVA containing 18% VA was melt blended with PLA in three ratios(80:20, 70:30, 60:40 wt%)  using a Twin screw extruder. EGMA was used as compatibilizer. Films were made by using a Tubular     Blown film extruder. The EVA-PLA blends were Tested for their mechanical, Thermal, Optical and Physical properties. The Blends were characterized by DSC, TGA and SEM. In the EVA-PLA blends, as the PLA concentration increases, the Tensile Strength in machine direction decreases. The tear strength of the EVA-PLA blends are better than EVA in both machine and transverse directions. The dart impact strength decreased, Luminious transmittance  decreased, WVTR increased, and Biodegradability percentage increased. However this much of improvements in tensile strength is sufficient for food packaging applications. Among the three composition 70:30 % (wt.%) yield best results. This is because of interaction between the polar groups of  EVA and PLA polymers  and also by  the   addition of  EGMA reactive  Compatibilizer. SEM images of the 70:30% blends   shows that EVA-PLA compatible and Partially Miscible. DSC curves of all composition of EVA-PLA blend show that the blend is partially miscible one.                                                                          

Author Biographies

Vinothkumar D, CIPET Chennai

M Tech Student Dept of Plastics Tech4

Soundararajan S, CIPET-IPT Guindy, Chennai-32 Tamil nadu INDIA

Dept of Plastics Tech, 5  (Former HOD)

References

REFERENCES

Arul Kumar K P and Soundararajan S. Studies on Mechanical, Barrier,

Optical and Physical Properties of LDPE/PLA Blend for Packaging Films.

J. Polym. Mater. 2016; 33: 491-502

Jaya Prakash N, Hari Pradsad S, Nehru S, Et al.

Synthesis, Characterization and Testing of Emulsion Polymerized Vinyl

Acetate –Acrylamide Copolymers for Bio-Degradable Applications. IOSR

Journal of Polymer and Textile Engineering (IOSR-JPTE). 2013; 1: 04-12

. Brydson J A. Plastics Materials, 7th Ed. USA Butter worth Hein mann Publishers. 1999.

-279.

Brydson J A. Plastics Materials, 7th Ed. USA Butter worth Hein mann Publishers. 1999.

Brydson J A. Plastics Materials, 7th Ed. USA Butter worth Hein mann Publishers. 1999.

, Do Van Cong, Thai Hoang, Nguyen Vu Giang, et al. A novel enzymatic

biodegradable route for PLA/EVA blends under agricultural soil of

Vietnam. Materials Science and

Engineering C. 2012; 32: 558–563.

Moura I, Botelho G and Machado A V. Characterization of EVA/PLA

blends when exposed to different environments . J Polym. Environment,

; 22: 148-157

Singla R K, Zafar M T, Maiti S N. et al. Physical blends of PLA with high

vinyl acetate containing EVA and their rheological,

thermo- mechanical and morphological responses. Polymer Testing, 2017;

: 398-406

Siti Najihah, Abdul Manan and Zurina Mohamad. Tensile Properties

and Morphology of Polylactic Acid (PLA)/ Ethylene Vinyl Acetate (EVA).

Applied Mechanics and Materials. 2015;735: 57-60.

Sunder Kelkar, Pravin Kadam, Shashank Mhaske et al.

Toughening of poly(lactic acid) by Ethylene-co-vinyl acetate

Copolymer having vinyl acetate Content of 18%: effect of ethylene co-

Vinyl acetate content, Advances in Materials Science and Engineering: An

International Journal. (MSEJ). 2014; 1: 27-37

Chi-hui Tsoul, Ya-Ming Li, Wei-Hua Yao et al.

Preparation and Characterization of Poly(lactic Acid)/ Ethylene Glycidyl

Methacrylate Copolymer Blends. Advanced Materials Research. 2011;150

-151: 139-143.

Fortunati E, Puglia D, Kenny J.M, et al. Effect of ethylene-co-vinyl

acetate-glycidyl methacrylate and cellulose microfibers on the thermal,

rheological and biodegradation properties of poly(lactic acid) based

systems. Polymer Degradation and Stability. 2013; 98: 2742- 2751.

Wei Yuan, Jianping Liu, Xia Song et al. The research of EVA to PLA/E-

AA-GMA blend materials toughening. Advanced Materials Research,

; 535-537: 1210-1213.

Kotiba Hamad, Mosab Kaseem and Fawaz Deri. Melt Rheology of

Poly(Lactic Acid)/Low Density Polyethylene Polymer Blends. Advances in

Chemical Engineering and Science, 2011; 1: P208-214.

ASTM Standards Annual Publication series – Volume 08-01.03

Additional Files

Published

2022-12-23

How to Cite

D, V., & S, S. (2022). Studies on Mechanical, Thermal, Optical, Physical Properties and Characterization of EVA-PLA blend Films with EGMA Compatibilizer. Journal of Polymer, Sustainability and Technology (ISSN: TBC), 7(1), 31–44. Retrieved from https://spaj.ukm.my/jpst/index.php/jpst/article/view/130

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