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Poly(vinylidene fluoride) nanofiber membrane with polypropylene support layer as a lithium-ion battery membrane

Davoud Amini, Erfan Oliaei, Mehdi Rajabi-Hamane, Hossein Mahdavi

Abstract


This work aims at preparation of poly(vinylidene fluoride) (PVdF) nanofiber membranes using electrospinning along with the use of polypropylene (PP) spunbonded non-woven fabric as its support for enhancing mechanical properties. Morphology and size of the membranes are studied by the scanning electron microscopy and optimum diameter of nanofibers are obtained by adjusting of electrospinning control factors. The tensile strength of the membrane increases from 39.67 to 52.75 MPa with the increase of spinning time from 1.5 to 2.0h. The studies of tensile behavior of membranes display that PP spunbonded fabric increases the tensile strength of prepared membranes. Thermal stability of the prepared membranes was determined using the TGA method and the dimensional stability was investigated by the measuring of shrinkage ratio at 105˚C. Shrinkage ratio, electrolyte uptake level and electrical resistance of the prepared membrane indicate its potential for battery separators.


Keywords


lithium-ion battery; membrane; electrospinning; poly(vinylidene fluoride) fibrous separator; polypropylene spunbonded fabric support

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References


M. Yanilmaz, M. Dirican, and X. Zhang, “Evaluation of electrospun SiO2/nylon 6,6 nanofiber membranes as a thermally-stable separator for lithium-ion batteries,” Electrochim. Acta, vol. 133, no. 0, pp. 501–508, Jul. 2014.

W. Li, Y. Wu, J. Wang, D. Huang, L. Chen, and G. Yang, “Hybrid gel polymer electrolyte fabricated by electrospinning technology for polymer lithium-ion battery,” Eur. Polym. J., vol. 67, no. 0, pp. 365–372, Jun. 2015.

D Amini, E. Oliaei, M. Rajabi-Hamane, and H. Mahdavi, “Polyvinylidene fluoride nanofiber coated polypropylene nonwoven fabric as a membrane for lithium-ion batteries,” FIBER POLYM, vol. 18, 2017, in press.

K. Hwang, B. Kwon, and H. Byun, “Preparation of PVdF nanofiber membranes by electrospinning and their use as secondary battery separators,” J. Memb. Sci., vol. 378, no. 1–2, pp. 111–116, Aug. 2011.

J. Hao, G. Lei, Z. Li, L. Wu, Q. Xiao, and L. Wang, “A novel polyethylene terephthalate nonwoven separator based on electrospinning technique for lithium ion battery,” J. Memb. Sci., vol. 428, no. 0, pp. 11–16, Feb. 2013.

S. Rajendran, M. R. Prabhu, and M. U. Rani, “Ionic conduction in poly(vinyl chloride)/poly(ethyl methacrylate)-based polymer blend electrolytes complexed with different lithium salts,” J. Power Sources, vol. 180, no. 2, pp. 880–883, Jun. 2008.

P. Carol, P. Ramakrishnan, B. John, and G. Cheruvally, “Preparation and characterization of electrospun poly(acrylonitrile) fibrous membrane based gel polymer electrolytes for lithium-ion batteries,” J. Power Sources, vol. 196, no. 23, pp. 10156–10162, Dec. 2011.

T. H. Cho, T. Sakai, S. Tanase, K. Kimura, Y. Kondo, T. Tarao, and M. Tanaka, “Electrochemical performances of polyacrylonitrile nanofiber-based nonwoven separator for lithium-ion battery,” Electrochem. Solid State Lett., vol. 10, no. 7, pp. A159–A162, 2007.

M. Buddhakala and A. Muakngam, “Morphology and thermal properties of PVDF electrospun nanofiber,” J. Appl. Sci. Res., vol. 9, no. 12, p. 5986, 2013.

H. Na, P. Chen, K.-T. Wan, S.-C. Wong, Q. Li, and Z. Ma, “Measurement of Adhesion Work of Electrospun Polymer Membrane by Shaft-Loaded Blister Test,” Langmuir, vol. 28, no. 16, pp. 6677–6683, Apr. 2012.

D. Yanhuai, P. Zhang, Z. Long, Y. Jiang, F. Xu, and W. Di, “Preparation of PVdF-based electrospun membranes and their application as separators,” Sci. Technol. Adv. Mater., vol. 9, no. 1, pp. 1–4, 2008.

M. Sethupathy, V. Sethuraman, and P. Manisankar, “Preparation of PVDF/SiO2 Composite Nanofiber Membrane Using Electrospinning for Polymer Electrolyte Analysis,” Soft Nanosci. Lett., vol. 3, no. 2, pp. 37–43, 2013.

W. Li, Y. Xing, Y. Wu, J. Wang, L. Chen, G. Yang, and B. Tang, “Study the effect of ion-complex on the properties of composite gel polymer electrolyte based on Electrospun PVdF nanofibrous membrane,” Electrochim. Acta, vol. 151, no. 0, pp. 289–296, Jan. 2015.

J. R. Kim, S. W. Choi, S. M. Jo, W. S. Lee, and B. C. Kim, “Electrospun PVdF-based fibrous polymer electrolytes for lithium ion polymer batteries,” Electrochim. Acta, vol. 50, no. 1, pp. 69–75, Nov. 2004.

Y. Chen, J. Guo, and H. Kim, “Preparation of poly(vinylidene fluoride)/phosphotungstic acid composite nanofiber membranes by electrospinning for proton conductivity,” React. Funct. Polym., vol. 70, no. 1, pp. 69–74, Jan. 2010.

Y. P. Mahant, S. B. Kondawar, M. Bhute, and D. V. Nandanwar, “Electrospun Poly (Vinylidene Fluoride)/Poly (Methyl Methacrylate) Composite Nanofibers Polymer Electrolyte for Batteries,” Procedia Mater. Sci., vol. 10, pp. 595–602, 2015.

W. W. Cuia, D. Y. Tang, and Z. L. Gong, “Electrospun poly(vinylidene fluoride)/poly(methyl methacrylate) grafted TiO2 composite nanofibrous membrane as polymer electrolyte for lithium-ion batteries,” J. Power Sources, vol. 223, pp. 206–213, 2013.

W. Chen, Y. Liu, Y. Ma, J. Liu, and X. Liu, “Improved performance of PVdF-HFP/PI nanofiber membrane for lithium ion battery separator prepared by a bicomponent cross-electrospinning method,” Mater. Lett., vol. 133, pp. 67–70, Oct. 2014.

D. Wu, C. Shi, S. Huang, X. Qiu, H. Wang, Z. Zhan, P. Zhang, J. Zhao, D. Sun, and L. Lin, “Electrospun Nanofibers for Sandwiched Polyimide/Poly (vinylidene fluoride)/Polyimide Separators with the Thermal Shutdown Function,” Electrochim. Acta, vol. 176, pp. 727–734, Sep. 2015.

N. Angulakshmi and A. M. Stephan, “Electrospun Trilayer Polymeric Membranes as Separator for Lithium–ion Batteries,” Electrochim. Acta, vol. 127, pp. 167–172, May 2014.

C. Cao, L. Tan, W. Liu, J. Ma, and L. Li, “Polydopamine coated electrospun poly(vinyldiene fluoride) nanofibrous membrane as separator for lithium-ion batteries,” J. Power Sources, vol. 248, pp. 224–229, Feb. 2014.

E. Oliaei, B. Kaffashi, and S. Davoodi, “Investigation of structure and mechanical properties of toughened poly(L-lactide)/thermoplastic poly(ester urethane) blends,” J. Appl. Polym. Sci., vol. 133, p. 43104, 2016.

H. Kuo-Shien, L. Huey-Shan, and C. Jeong-Bor, “Study on the Modification of PP Nonwoven Fabric,” FIBRES TEXT EAST EUR, vol. 19, no. 3, pp. 82–87, 2011.

E. Oliaei and B. Kaffashi, “Investigation on the properties of poly (L-lactide)/thermoplastic poly (ester urethane)/halloysite nanotube composites prepared based on prediction of halloysite nanotube location by measuring free surface energies,” Polymer, vol. 104, p. 104-114, 2016.

Y. Shen and A. C. Lua, “Preparation and characterization of mixed matrix membranes based on poly(vinylidene fluoride) and zeolite 4A for gas separation,” Polym. Eng. Sci., vol. 52, no. 10, pp. 2106–2113, 2012.

B. Jaleh, N. Gavary, P. Fakhri, N. Muensit, and S. M. Taheri, “Characteristics of PVDF Membranes Irradiated by Electron Beam,” Membranes (Basel)., vol. 5, no. 1, pp. 1–10, 2015.


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